Opportunistic mobility with multipath TCP

Proceedings of: ACM MobiArch 2011, The 6th ACM International Workshop on Mobility in the Evolving Internet Architecture, June 28, 2011, Washington, D.C.Host mobility has traditionally been solved at the network layer, but even though Mobile IP has been standardised for 15 years, it hasn’t been supported by operators. IP’s double role as a location identif er and communication endpoint identif er brings a number of functional and performance problems. We argue that the best place to handle mobility is at the transport layer. While this is not a new argument, we believe that the emerging standard of Multipath TCP (MPTCP) can be used to solve many issues related to mobility. MPTCP naturally implements make-before-break, can be incrementally deployed, is backwards compatible with standard TCP, and could even ease incremental adoption of IPv6. Using simulations and indoor experiments with WiFi and 3G, we show that MPTCP gives better throughput, achieves smoother handoffs, and can be tuned to lower energy consumption.This research was supported by Trilogy (http://www.trilogy-project.org), a research project (ICT-216372) partially funded by the European Community under its Seventh Framework Programme. European Community's Seventh Framework ProgramThis work was partly funded by POSDRU/89/1.5/S/62557Publicad

Synthesis and Solvent Dependent Fluorescence of Some Piperidine-Substituted Naphthalimide Derivatives and Consequences for Water Sensing

Novel fluorescent strigolactone derivatives that contain the piperidine-substituted 1,8-naphthalimide ring system connected through an ether link to a bioactive 3-methyl-furan-2-one unit were synthesized and their spectroscopic properties investigated. The solvatochromic behavior of these piperidine-naphthalimides was monitored in solvents of different polarity using the electronic absorption and fluorescence spectra. These compounds exhibited a strong positive solvatochromism taking into account the change of solvent polarity, and the response mechanism was analyzed by fluorescence lifetime measurements. According to Catalan and [f(n), f(ε), β, α] solvent scales, the dipolarity and polarizability are relevant to describe the solute–solvent interactions. The emission chemosensing activity was discussed in order to determine the water content in organic environments. The emission intensity of these compounds decreased rapidly in dioxane, increasing water level up to 10%. Measuring of quantum yield indicated that the highest values of quantum efficiency were obtained in nonpolar solvents, while in polar solvents these derivatives revealed the lowest quantum yield. The fluorescence decay can be described by a monoexponential model for low water levels, and for higher water contents a biexponential model was valid